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The below is also valid for EndNote 20.
The EndNote library
An EndNote library is made up of a file with the extension *.enl plus a corresponding *.DATA folder. Both units make up a complete library, and they both need to have the exact same name and need to be located at the same location, see picture below.
Backup of the library
The simplest way to send (or make a backup) of your library is via the "Compressed Library"-function in EndNote.
You find it in EndNote X9 under File>Compressed Library (.enlx)...
How to use/restore your backed-up library
First place the backup file where you want the library (Storage location for Endnote libraries).
When you want to recreate a functional library from the compressed file just open the file like you would a normal library and EndNote will do the rest.